Ministry of Lands and Mineral Resources

Fiji Mineral Resources Department

MINERALS

WHAT ARE MINERALS?

The rocks which form the Earth, the Moon and the planets are made up of minerals. Minerals are chemical elements or compounds which occur naturally within the crust of the Earth. They are the discrete crystalline particles of which nearly all rocks are made. Minerals are solid substances made up of atoms with an orderly and regular arrangement, which is the basis of their crystalline state. Because of their orderly atomic arrangement it is also possible to express the composition of a mineral as a chemical formula.

Minerals are inorganic substances (not derived from living things) composed of elements such as silica, oxygen, aluminium, iron, etc. Fossil fuels such as coal, oil and natural gas are organic (formed from once-living matter) and hence are not minerals in the strict sense.

Minerals provide the elements essential to life, the metals of industry and the materials for building (Tables 2-7). The calcium and phosphorus in bones and the iron in blood are made available to the body through plants which extract these elements from minerals in the soil.

Mineralogists (geologists who study minerals) have identified nearly 3000 minerals. About 100 of these are regarded as common minerals and less than 20 can be found everywhere.

Nearly all rocks are composed of minerals (some contain glass or organic matter) but it is rare to find good mineral specimens. These tend to occur in gaps, cavities and fractures within the rocks where the crystals have been unobstructed (have much free space) during their growth. Rocks can be formed from a combination of several different minerals or a single mineral can make up the bulk of a rock, for example, limestone or marble is mainly composed of the mineral calcite (CaCO3).

GENERAL CHARACTERISTICS

Many minerals are found as beautiful crystals. Crystals are formed when minerals are free to grow without constraint. Crystal faces reflect the regular atomic arrangement of the mineral. The incredibly regular arrangement of crystals has been recognised for about 200 years but the internal structure of minerals has only been determined this century by the use of X-rays. The regularity of crystals is due to the angle between the same two faces of all crystals of the same mineral species being constant, even though the faces may look variable in size and shape. This crystal structure determines the physical properties of minerals. Crystals are symmetrical and can be grouped according to their symmetry into seven crystal systems. The study of crystals and crystal systems is called crystallography.

Minerals vary in colour and in the way they look and feel. Some minerals are hard and sparkle and shine like glass. Others are slippery and soft or hard and scratchy. The way minerals look depends on their interaction with light, and these optical properties can be used to classify and identify minerals. These include properties such as transparency, reflection and refraction, lustre, colour, streak (colour of the powdered mineral) and fluorescence.

Minerals can be classified according to their hardness as described by Moh's Hardness Scale (Table 1). In 1812, F. Mohs arranged ten minerals in order of hardness so that each mineral can be scratched by the one following it on the scale. Thus talc is the softest and diamond is the hardest.

Table 1. Moh's Scale of Hardness

Hardness Mineral Objects of Similar Hardness Mnemonic
1 Talc Dry soap The
2 Gypsum Plaster of Paris Ground
3 Calcite Finger nail Can
4 Fluorite Copper Coin Form
6 Apatite Pen knife A
6 Feldspar Glass Fault
7 Quartz Hardened knife Quickly
8 Topaz Grinding wheel Terrifying
9 Corundum Garnet paper Cheerful
10 Diamond Diamond Dinosaurs

Minerals also occur as aggregates of crystals that rarely show perfect crystal shapes. The form of the aggregate can be useful for identification, i.e. whether they are fibrous, dendritic, lamellar or foliated, etc.

The density or specific gravity of a mineral depends on several factors including the kind of atoms in the structure and how closely they are packed. For example, the minerals tridymite and quartz are both silica (SiO2) but quartz, the closely packed form, has a specific gravity of 2.65 at room temperature whereas tridymite, with a more open structure, has a specific gravity of 2.26 at room temperature.

Other properties that mineralogists use when identifying and classifying minerals are related to how they break i.e. cleavage (breaks along a planar surface related to the structure and parallel to a possible crystal face) and fracture (broken surface is irregular), magnetic, electrical and radioactive properties.

The composition of a mineral can be expressed as a chemical formula which is a simple way of expressing mineral chemistry. The mineral chemistry can be used to further classify minerals. Silicate minerals (combinations of silicon and oxygen with other elements) are the most abundant rock-forming minerals. Silicate minerals that commonly occur in the rocks of Fiji include feldspar, mica, olivine, pyroxene and amphibole. Quartz is simply a combination of oxygen and silicon, without other elements.

TYPES OF MINERALS

There are two types of minerals: metals and non-metals, and they have different properties as outlined below.

Metals

  • Strong, can support heavy loads without breaking.

  • Conduct heat and electricity.

  • Opaque - do not allow light to pass through.

  • Malleable - can be bent without breaking.

  • Ductile - can be stretched into wire.

Non-Metals

  • Weak, shatter when hit with a hard object.

  • Most do not conduct heat and electricity.

  • Can be transparent, translucent or opaque.

  • Not malleable.

  • Not ductile.

ORIGIN OF MINERALS AND ROCKS

Most minerals crystallise from some sort of solution. Some of the ways minerals can form are from :

(i) cooling of magma (complex solutions of molten rock materials within the earth) or lava (complex solutions of molten rock material that reach the Earth's surface);

(ii) cooling of subsurface solutions involving hot water or hot gases, including steam, as in many mineral veins and metallic ore deposits;

(iii) hot vapours condensing to form minerals, such as sublimates of sulphur near volcanic vents;

(iv) chemical reactions with previous minerals, such as the hydrothermal alteration of feldspar to mica, or the oxidation of iron-bearing minerals in the zone of chemical weathering at the earth's surface;

(v) replacement or substitution of an earlier-formed mineral;

(vi) recrystallisation of earlier-formed minerals to form new compounds under changed temperature and pressure conditions; or

(vii) evaporation of water solutions.

ORE MINERALS

Many minerals are useful to us. A useful mineral from which a valuable element can be extracted is called an ore mineral. Ore is a rock that has enough concentration of one or more such minerals to make it profitable to mine it. Mineral ores are the source of all the metals and many other substances that we use every day (Table 5). To obtain these Earth resources we have to take them out of the Earth by mining and then change them into different substances. Ore also contains economically useless gangue minerals which have to be removed before the ore minerals can be concentrated.

USES OF MINERALS

Minerals have always been used by humans in almost every facet of daily living. Primitive peoples who used rocks to form weapons and other useful tools in the Stone Age. Then, as people discovered the methods of isolating metals from their mineral ores, "technology" and "civilisation" advanced successively through the Copper, Bronze, Iron, Steel and Atomic Ages. At each step, minerals assumed progressively greater importance.

The tables below (Tables 2-7) represent some of the common minerals and their many uses in our everyday lives.

Table 2. Uses of Some Common Metallic Minerals

EXTRACTED METAL METALLIC MINERAL ORES CHEMICAL MAKEUP USES
Aluminum, Al Bauxite Al2O3.2H2O Beverage and food cans, furniture, buildings, electrical appliances, air conditioners, ships, motor vehicles, aircraft and other transport equipment, cooking utensils, aluminium foil, high voltage power transmission lines (with steel core).
Chromium, Cr Chromite FeCr2O4 Plating household appliances, motor cars, to harden and strengthen steels and cast iron, stainless steel for automotive, construction and chemical industries.
Copper, Cu Native Copper Chalcopyrite Chalcocite

Bornite

Cu

CuFeS2

Cu2S

Cu5FeS4

All electrical appliances, telephone cables, radios, TV sets, motor vehicle electrical systems, motors for all purposes, ornamental items made of brass and bronze, plumbing pipes and tanks, roofing.
Gold, Au Gold Au Currency, jewellery, dentistry, electronic and space technology.
Iron, Fe

and steel

Hematite Magnetite Limonite

Siderite

Fe2O3

Fe3O4

2Fe2O3.3H2O

FeCO3

Household appliances, motor vehicles, buildings, bridges, office equipment, beverage and food cans and other containers, tools, farm and factory machinery, transport equipment, building materials.
Lead, Pb Galena

Cerussite

PbS

PbCO3

Storage batteries, petrol additives, buildings, bridges, office equipment, beverage and food cans and other containers, tools, farm and factory machinery, transport equipment, building materials.
Nickel, Ni Pentlandite

Garnierite

(FeNi)9S8

(Ni,Mg)SiO3.nH2O

Stainless steel, motor vehicles plating, aircraft, transport equipment, household appliances, electrical machinery, ships, coinage, numerous alloys particularly where corrosion resistance and hardeners are important requirements.
Silver, Ag Native Silver Argentite Ag

AgS

Photographic film and developing paper, silverware, jewellery, industrial refrigerators, coinage, batteries, electronic solder in aircraft.
Tin, Sn Cassiterite SnO2 Tin plate, solder, pewterware, in bronze, in electrical equipment, in pigments for pints and plastics and in dry-cell batteries.
Titanium, Ti Ilmenite

Rutile

FeTiO3

TiO2

Ti metal for engines, Ti pigment for paints, paper, plastics, welding electrodes.
Uranium, U Pitchblende or Uraninite,

Yellow-cake

UO3

U3O8

Power generation, production of radioisotopes for research, industry, agriculture and medicine.
Zinc, Zn Sphalerite

Smithsonite

ZnS

ZnCO3

Galvanised roofs, fences, car bodies, zinc die castings for carburettors, motor vehicle grills, household appliances, door handles, zinc oxides for tyres and paints, rolled zinc

in dry-cell batteries.

Table 3. Uses of Some Non-Metallic Minerals

Asbestos Fireproof fabrics, paper, brake linings
Barite Oil-well drilling muds, glass, paint
Borates Flux, glass, detergents, chemicals
Clays Bricks, tiles, pottery, fillers for paint, rubber and paper, decolourisers
Diamond Drills, abrasives, gems
Feldspar Flux for glass manufacture, porcelain, enamel, tile glazes, abrasives, toothpaste
Fluorite Glass, enamel
Garnet Abrasives, gems, watches, jewels
Graphite Pencils, batteries, foundry facings, crucibles, lubricants
Gypsum Wallboard, plaster, soil improvement, retarder in portland cement
Halite (salt) Food, Chlorine for water treatment, sodium hydroxide for soap
Magnesia Cements, rubber, foundries, refractory brick
Mica Electronics, radio tubes, electrical insulation, cement, paint
Olivine Refractories, gems
Quartz Broadcast frequency control, silica glass
Sulphur Fertiliser, sulphuric acid, paper making, bleaches
Talc Toiletries, ceramics, paint, paper
Vermiculite Sound insulation in plaster and loose fill, plastics

Table 4. Minerals Used in a School Room

Blackboard Made of wood covered with paint containing abrasive minerals such as ground pumice. Duster made of synthetic fibre.
Cement Made from clays, shale, limestone, bauxite, hematite, gypsum
Chalk Dried and moulded paste of calcium carbonate and gypsum
Desks Frames of steel painted or galvanised with zinc
Glass Made from silica sand, limestone, borate salts, soda ash and feldspar minerals
Paper Filled or coated with industrial minerals like kaolin, calcium carbonate and talc
Pens, pencils Graphite and clays in pencils. Ballpoint pens use brass, tungsten and plastic. Ink uses calcium carbonate and fillers.
Walls Wallboard of gypsum joined by cement with gypsum, mica, clays and calcium carbonate
Wood Saws and planes made from steel are used to cut wood. Wood is sanded with sand paper embedded with emery, corundum and garnet powders

Table 5. Minerals Used in a Bathroom

Cistern PVC and plastics from petrochemicals and components of brass
Cleaners Sterilants and bleaches made with chlorine and halite. Scouring and cleaning liquids and soap made from soda ash, borax, limestone, halite, sulphur, clays, diatomite, pumice and petrochemicals
Cosmetics Talc in powder, magnesium carbonate and silica help flow and fragrance. Lipsticks use talc and calcium carbonate
Countertops Marble and granite or ceramic
Hand basin and bath Porcelain made using silica, limestone, borate salts, soda ash and titanium minerals
Shampoo Clays used as thickeners
Tap fittings Brass, steel or aluminium with plastic components. Chrome uses chromium, cadmium, sulphur
Tiles Ceramics are made from kaolin, silica, feldspar, talc. Manganese, cobalt, antimony and iron oxides give colour. Putty uses limestone and gypsum
Toilet paper Pulp is processed with sulphur, soda ash, limestone, clay, talc and titanium minerals
Toothpaste Calcium carbonate, zeolites, sodium carbonate and clays. Gels use silica.

Table 6. Minerals used in Sporting Equipment

Bicycles Frame, wheels and gearing are of steel, aluminium, chromium and titanium minerals. The plastic seat and helmet are from petrochemicals. The tyres made using sulphur and petrochemicals
Skateboard Iron, chromium, nickel, petrochemicals, aluminium. Pads and helmet use copper, zinc, petrochemicals and iron.
Sneakers Plastics, dyes, synthetic fibres and printing ink for the tough fabric come from petrochemicals. Petrochemicals and sulphur used in the rubber soles.
Sun creams Made with zinc compounds and titanium oxides
Sunglasses Lenses of glass or plastics from petrochemicals. Frames of chromium, brass and gold
Roller blades The plastics, nylon and synthetic fibres from petrochemicals, while the metal parts are aluminium, steel or brass.

Table 7. Minerals Used in Furniture, Fittings and other Equipment

Aircraft Made of aluminium, chromium, cobalt, tantalum, and titanium.
Carpets Wool is cleaned with clays, soda ash, zeolite or petrochemicals. Synthetic fibres and dyes come from petrochemicals
Chairs Frame made of steel painted or galvanised with zinc. Coverings of vinyl and synthetic fibres derived from petrochemicals
Computers and electronics More than 33 minerals and elements ranging from aluminium to zirconium. The silicon chip is made from silica or quartz
Curtains Made of natural or synthetic fibres. Tracks are of aluminium or steel.
Door Handles Made from steel or brass (alloy of copper and zinc)
Door stopper and other rubber items Made from petrochemicals, sulphur, limestone and clays
Fireworks Sulphur; colours from mineral mixtures like iron filings and charcoal (gold sparks), strontium and sodium (orange), barium (green), strontium (red), copper (blue), sodium (yellow), and others. Fine aluminium powder is used for a loud flash.
Floors Concrete uses lightweight aggregate such as perlite, vermiculite, zeolite or expanded shales. Floors covered with ceramic, marble or granite tiles
Light bulbs, fluorescent tubes Made from glass. Metal fittings of steel, copper and lead. Elements of tungsten and rare earth metals.
Light switches Made of steel, copper and brass, with plastic components from petrochemicals
Linoleum Made from petrochemicals, and also contain clays, limestone and wollastonite
Medicine Contain minerals like kaolin, iodine, and many others
Metallic window frames Made of steel and aluminium
Telephones A telephone handset uses 42 different minerals!
Paints Most are made from petrochemicals, but contain minerals such as calcium carbonate (from limestone), clays, hematite, talc, mica, petrochemicals, and colouring pigments from titanium minerals
Whiteboard Steel or aluminium frame covered with plastic sheeting from petrochemicals
Windows Sheeting made by floating glass on molten tin.

NECESSITY OF MINERALS

Today, mineral resources play a role second in importance only to that of agriculture, and there are thousands of uses for the various materials of the Earth. There isn't much that one can think of that doesn't come from some sort of mining process and it can honestly be said that:

"If it's not grown, it's mined"!

Virtually no aspect of our lifestyle could be sustained without minerals. Minerals are used in every facet of our daily living from food production and processing, building, providing shelter/housing to transport, communications, medicine and leisure activities.

EXPLORATION AND MINING

Exploration is the search for mineral deposits containing sufficient ore to be economically mined. Geologists use all available geological and geophysical tools to assist exploration. Ore minerals are extracted from the Earth's surface and from underground by mining. The ore is then milled, (crushed), processed and refined to produce the metal or non-metallic product.

FIJI'S MINERAL WEALTH

Fiji's mineral wealth includes gold which is mined at Vatukoula and provides the fourth largest source of foreign exchange. There are plans to open gold mines at Mt Kasi in south-west Vanua Levu and at Tuvatu near Nadi. Advanced exploration is also currently underway at Namosi for copper-gold, at Wainivesi for marble and in other parts of Fiji for gold. In addition, there is quarrying of rock and sand for road metal, concrete aggregate and landfill and of coral sand for cement manufacture. Clay is used by many villagers to make pottery.


SUGGESTIONS FOR FURTHER READING

Allison, I. S. & Palmer, D. F. 1980. Geology, the science of a changing Earth. VII Edition. McGraw-Hill Inc.

Cox, K. G., Price, N. B. & Harte, B. 1974. An Introduction to the Practical Study of Crystals, Minerals and Rocks. Rev. 1st ed., John Wiley & Sons Inc., New York.

Hamilton, W. R., Woolley, A. R. & Bishop, A. C. 1984. The Hamlyn Guide to Minerals, Rocks and Fossils. The Hamlyn Publishing Group Ltd, London.

Lye, K. 1979. Minerals and Rocks, (Kingfisher Guides), Ward Lock Ltd., London.

MRD Information Notes 8

ISSN 1016-2135

Director : A. Rahiman

Devika P. Reddy

August 1995

ISSN 1016-2135